Wetting of a plane with a narrow solvophobic stripe
File(s)TMPH-2018-0032_Revised_Manuscript.pdf (580.46 KB)
Accepted version
Author(s)
Yatsyshin, P
Parry, AO
Rascon, C
Kalliadasis, S
Type
Journal Article
Abstract
We present a numerical study of a simple density functional theory model of fluid
adsorption occurring on a planar wall decorated with a narrow deep stripe of a
weaker adsorbing (relatively solvophobic) material, where wall-fluid and fluid-fluid
intermolecular forces are considered to be dispersive. Both the stripe and outer
substrate exhibit first-order wetting transitions with the wetting temperature of
the stripe lying above that of the outer material. This geometry leads to a rich
phase diagram due to the interplay between the pre-wetting transition of the outer
substrate and an unbending transition corresponding to the local evaporation of
liquid near the stripe. Depending on the width of the stripe the line of unbending
transitions merges with the pre-wetting line inducing a two-dimensional wetting
transition occurring across the substrate. In turn, this leads to the continuous pre-
drying of the thick pre-wetting film as the pre-wetting line is approached from above.
Interestingly we find that the merging of the unbending and pre-wetting lines occurs
even for the widest stripes considered. This contrasts markedly with the scenario
where the outer material has the higher wetting temperature, for which the merging
of the unbending and pre-wetting lines only occurs for very narrow stripes.
adsorption occurring on a planar wall decorated with a narrow deep stripe of a
weaker adsorbing (relatively solvophobic) material, where wall-fluid and fluid-fluid
intermolecular forces are considered to be dispersive. Both the stripe and outer
substrate exhibit first-order wetting transitions with the wetting temperature of
the stripe lying above that of the outer material. This geometry leads to a rich
phase diagram due to the interplay between the pre-wetting transition of the outer
substrate and an unbending transition corresponding to the local evaporation of
liquid near the stripe. Depending on the width of the stripe the line of unbending
transitions merges with the pre-wetting line inducing a two-dimensional wetting
transition occurring across the substrate. In turn, this leads to the continuous pre-
drying of the thick pre-wetting film as the pre-wetting line is approached from above.
Interestingly we find that the merging of the unbending and pre-wetting lines occurs
even for the widest stripes considered. This contrasts markedly with the scenario
where the outer material has the higher wetting temperature, for which the merging
of the unbending and pre-wetting lines only occurs for very narrow stripes.
Date Issued
2018-06-01
Date Acceptance
2018-04-23
Citation
Molecular Physics, 2018, 116, pp.1990-1997
ISSN
0026-8976
Publisher
Taylor & Francis
Start Page
1990
End Page
1997
Journal / Book Title
Molecular Physics
Volume
116
Copyright Statement
© 2018 Informa UK Limited, trading as Taylor & Francis Group. This is an Accepted Manuscript of an article published by Taylor & Francis in Molecular Physics on 01 June 2018, available online: https://www.tandfonline.com/doi/full/10.1080/00268976.2018.1473648
Sponsor
Engineering & Physical Science Research Council (EPSRC)
Commission of the European Communities
Engineering & Physical Science Research Council (EPSRC)
Engineering & Physical Science Research Council (E
Identifier
https://www.tandfonline.com/doi/full/10.1080/00268976.2018.1473648
Grant Number
EP/L020564/1
247031
EP/L027186/1
EP/R511547/1
Subjects
Science & Technology
Physical Sciences
Chemistry, Physical
Physics, Atomic, Molecular & Chemical
Chemistry
Physics
Wetting
classical density functional theory
DENSITY-FUNCTIONAL THEORY
CAPILLARY CONDENSATION
FILMS
TRANSITION
FLUIDS
ADSORPTION
SURFACE
WEDGE
MODEL
INTERFACE
0202 Atomic, Molecular, Nuclear, Particle and Plasma Physics
0306 Physical Chemistry (incl. Structural)
0307 Theoretical and Computational Chemistry
Chemical Physics
Publication Status
Published
Date Publish Online
2018-06-01