Scaling of wetting and pre-wetting transitions on nano-patterned walls
File(s)scaling_chem_het_wall_18.7..pdf (584.47 KB)
Accepted version
Author(s)
Parry, Andrew
Malijevsky, Alex
pospisil, martin
laska, martin
Type
Journal Article
Abstract
We consider a nanopatterned planar wall consisting of a periodic array of stripes of width L, which are
completely wet by liquid (contact angle θ = 0), separated by regions of width D which are completely dry
(contact angle θ = π). Using microscopic density functional theory, we show that, in the presence of long-ranged
dispersion forces, the wall-gas interface undergoes a first-order wetting transition, at bulk coexistence as the
separation D is reduced to a value Dw ∝ ln L, induced by the bridging between neighboring liquid droplets.
Associated with this is a line of prewetting transitions occurring off coexistence. By varying the stripe width L,
we show that the prewetting line shows universal scaling behavior and data collapse. This verifies predictions
based on mesoscopic models for the scaling properties associated with finite-size effects at complete wetting
including the logarithmic singular contribution to the surface free energy
completely wet by liquid (contact angle θ = 0), separated by regions of width D which are completely dry
(contact angle θ = π). Using microscopic density functional theory, we show that, in the presence of long-ranged
dispersion forces, the wall-gas interface undergoes a first-order wetting transition, at bulk coexistence as the
separation D is reduced to a value Dw ∝ ln L, induced by the bridging between neighboring liquid droplets.
Associated with this is a line of prewetting transitions occurring off coexistence. By varying the stripe width L,
we show that the prewetting line shows universal scaling behavior and data collapse. This verifies predictions
based on mesoscopic models for the scaling properties associated with finite-size effects at complete wetting
including the logarithmic singular contribution to the surface free energy
Date Issued
2019-09-03
Date Acceptance
2019-08-22
Citation
Physical Review E: Statistical, Nonlinear, and Soft Matter Physics, 2019, 100, pp.032801-1-032801-5
ISSN
1539-3755
Publisher
American Physical Society
Start Page
032801-1
End Page
032801-5
Journal / Book Title
Physical Review E: Statistical, Nonlinear, and Soft Matter Physics
Volume
100
Copyright Statement
©2019 American Physical Society.
Sponsor
Engineering & Physical Science Research Council (EPSRC)
Identifier
https://journals.aps.org/pre/abstract/10.1103/PhysRevE.100.032801
Grant Number
EP/L020564/1
Subjects
Fluids & Plasmas
01 Mathematical Sciences
02 Physical Sciences
09 Engineering
Publication Status
Published online
Date Publish Online
2019-09-03