Measurements and modelling of the viscosity of six synthetic crude oil mixtures
File(s)
Author(s)
Malta, J Álvaro MSC
Calabrese, Claudio
Nguyen, Thanh-Binh
Trusler, JP Martin
Vesovic, Velisa
Type
Journal Article
Abstract
The viscosity and density are reported for six synthetic mixtures, composed of up to 13 components, designed to match a light, dead crude oil of API 32° and molar mass of approximately 184 g mol−1. The measurements were made in the liquid region at temperatures between (323 and 398) K and in the pressure range from 1 MPa to 70 MPa. The viscosity was measured with a vibrating-wire viscometer, while the density was measured by means of a vibrating U-tube densimeter. The density and viscosity data have expanded relative uncertainties of 0.12% and 1.2%, respectively with a coverage factor of 2.
We have used the measured viscosity data to test the predictive power of the four viscosity models, the extended hard sphere (EHS), one-component EHS (1-cEHS), three-component EHS (3-cEHS) and Vesovic-Wakeham (VW), that have their basis in kinetic theory and the molecular description of the fluid. Two of the models (EHS and VW) require full compositional description of the mixture, while the other two belong to a new family of models which dispense with full compositional characterization, but retain molecular description. On average the EHS and VW models predict the viscosity data with lower deviations than 1-cEHS and 3-cEHS models, but all four models represent the data with uncertainty of 5–10%.
We have used the measured viscosity data to test the predictive power of the four viscosity models, the extended hard sphere (EHS), one-component EHS (1-cEHS), three-component EHS (3-cEHS) and Vesovic-Wakeham (VW), that have their basis in kinetic theory and the molecular description of the fluid. Two of the models (EHS and VW) require full compositional description of the mixture, while the other two belong to a new family of models which dispense with full compositional characterization, but retain molecular description. On average the EHS and VW models predict the viscosity data with lower deviations than 1-cEHS and 3-cEHS models, but all four models represent the data with uncertainty of 5–10%.
Date Issued
2020-02-01
Date Acceptance
2019-10-01
Citation
Fluid Phase Equilibria, 2020, 505
ISSN
0378-3812
Publisher
Elsevier BV
Journal / Book Title
Fluid Phase Equilibria
Volume
505
Copyright Statement
© 2019 Elsevier Ltd. All rights reserved. This manuscript is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International Licence http://creativecommons.org/licenses/by-nc-nd/4.0/.
Sponsor
Qatar Shell Research and Technology Center QSTP LLC
Grant Number
490000724
Subjects
0203 Classical Physics
0904 Chemical Engineering
Chemical Engineering
Publication Status
Published
Article Number
112343
Date Publish Online
2019-10-02