Operando XAFS of supported Pd nanoparticles in flowing ethanol/water mixtures: Implications for catalysis.
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Author(s)
Type
Journal Article
Abstract
Ethanol-water, a prototypical ‘green’ solvent mixture, cannot be considered as inert toward supported Pd nanoparticles. We establish severe size dependencies in Pd redox behavior, persistent gradients in Pd phase in a plug-flow situation, and that Pd nanoparticles are contaminated with hydrogen derived from the solvent.
Date Issued
2016-01-21
Date Acceptance
2015-08-07
Citation
Green Chemistry, 2016, 18 (2), pp.406-411
ISSN
1744-1560
Publisher
Royal Society of Chemistry
Start Page
406
End Page
411
Journal / Book Title
Green Chemistry
Volume
18
Issue
2
Copyright Statement
Open Access Article. Published on 12 August 2015. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. This journal is © The Royal Society of Chemistry 2015
License URL
Sponsor
Engineering & Physical Science Research Council (EPSRC)
Engineering & Physical Science Research Council (E
Grant Number
EP/G070172/1
EP/L003279/1
Subjects
Organic Chemistry
03 Chemical Sciences
Publication Status
Published
Date Publish Online
2015-08-12