Belite-ye'elimite-ferrite cements produced from London Clay
File(s)
Accepted version
Author(s)
Yio, Marcus
Ng, Yi
Hou, Pengkun
Chun Chan, Tsz
Wong, Hong
Type
Journal Article
Abstract
London Clay (LC) is generated in significant quantities from major infrastructure development projects within and around London. Excavated LC spoils are typically landfilled or used for landscaping purposes with minimal value. This study investigates the feasibility of producing belite-ye'elimite-ferrite (BYF) cements using London Clay (LC) in combination with kaolin or low-grade bauxite. Six cement clinkers with varying compositions were synthesised at 1300°C. The phase composition of the synthesised clinkers was quantified using XRD coupled with Rietveld refinement. The hydration behaviour, phase assemblage evolution, and mechanical performance of the cements were examined using isothermal calorimetry, XRD, TGA, and compressive strength testing respectively, up to 90 days of curing. It is demonstrated that LC can be used either on its own or with kaolin or low-grade bauxite to produce BYF cements with a wide range of composition: 31 to 64 wt.% belite, 9.3 to 27 wt.% ye'elimite and 2.1 to 31% ferrite. The use of LC as the sole alumina source resulted in low compressive strength at early stages. Nevertheless, the strength developed over time, reaching 27.8 MPa at 90 d (0.5 w/b). Possible approaches to develop LC further for producing viable BYF cements are discussed.
Date Issued
2025-02-01
Date Acceptance
2024-08-29
Citation
Advances in Cement Research, 2025, 37 (2), pp.67-77
ISSN
0951-7197
Publisher
ICE Publishing
Start Page
67
End Page
77
Journal / Book Title
Advances in Cement Research
Volume
37
Issue
2
Copyright Statement
Copyright © 2024 Emerald Publishing Limited. This is the author’s accepted manuscript made available under a CC-BY licence in accordance with Imperial’s Research Publications Open Access policy (www.imperial.ac.uk/oa-policy)
License URL
Identifier
http://dx.doi.org/10.1680/jadcr.23.00239
Publication Status
Published
Date Publish Online
2025-02-17