Possible application of stable isotope compositions for the identification of metal sources in soil
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Accepted version
Supporting information
Author(s)
Type
Journal Article
Abstract
Metals in soil are potentially harmful to humans and ecosystems. Stable isotope measurement may provide "fingerprint" information on the sources of metals. In light of the rapid progress in this emerging field, we present a state-of-the-art overview of how useful stable isotopes are in soil metal source identification. Distinct isotope signals in different sources are the key prerequisites for source apportionment. In this context, Zn and Cd isotopes are particularly helpful for the identification of combustion-related industrial sources, since high-temperature evaporation-condensation would largely fractionate the isotopes of both elements. The mass-independent fractionation of Hg isotopes during photochemical reactions allows for the identification of atmospheric sources. However, compared with traditionally used Sr and Pb isotopes for source tracking whose variations are due to the radiogenic processes, the biogeochemical low-temperature fractionation of Cr, Cu, Zn, Cd, Hg and Tl isotopes renders much uncertainty, since large intra-source variations may overlap the distinct signatures of inter-source variations (i.e., blur the source signals). Stable isotope signatures of non-metallic elements can also aid in source identification in an indirect way. In fact, the soils are often contaminated with different elements. In this case, a combination of stable isotope analysis with mineralogical or statistical approaches would provide more accurate results. Furthermore, isotope-based source identification will also be helpful for comprehending the temporal changes of metal accumulation in soil systems.
Date Issued
2021-04-05
Date Acceptance
2020-12-05
Citation
Journal of Hazardous Materials, 2021, 407
ISSN
0304-3894
Publisher
Elsevier
Journal / Book Title
Journal of Hazardous Materials
Volume
407
Copyright Statement
© 2020 Elsevier B.V. All rights reserved. This manuscript is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International Licence http://creativecommons.org/licenses/by-nc-nd/4.0/
Sponsor
Commission of the European Communities
Commission of the European Communities
Identifier
https://www.ncbi.nlm.nih.gov/pubmed/33340973
PII: S0304-3894(20)32803-X
Grant Number
PIEF-GA-2012-329878
702916
Subjects
Heavy metals
Isotope fractionation
Soil contamination
Source apportionment
Stable isotopes
Publication Status
Published
Coverage Spatial
Netherlands
Article Number
ARTN 124812
Date Publish Online
2020-12-10