Enhancing the fracture resistance and impact toughness of mechanically frothed epoxy foams with hollow elastomeric microspheres
File(s)Revised Manuscript.pdf (9.44 MB)
Accepted version
Author(s)
Song, W
Tagarielli, VL
Lee, KY
Type
Journal Article
Abstract
Nonporous elastomeric particles are often employed to improve the toughness of brittle epoxy foams but this also decreases their compressive strength and stiffness. Herein, a novel strategy utilizing hollow elastomeric microspheres as toughening agent for epoxy foams is presented. The addition of 0.5 wt.% hollow elastomeric microspheres into epoxy foam leads to a 15% increase in critical stress intensity factor (K1c) to 0.38 MPa m0.5and 33% increase in Charpy impact strength (acU) to 1.05 kJ m−2, respectively, compared to unfilled epoxy foam (K1c = 0.33 MPa m0.5and acU= 0.79 kJ m−2). However, a further increase in the hollow elastomeric microsphere concentration to 1.0 wt.% leads to microsphere agglomeration, which reduces both K1cand acUto 0.35 MPa m0.5and 0.93 kJ m−2, respectively. Nevertheless, the added hollow elastomeric microspheres do not lead to a reduction in the quasi-static compressive properties of the epoxy foams.
Date Issued
2018-12-01
Date Acceptance
2018-08-14
Citation
Macromolecular Materials and Engineering, 2018, 303
ISSN
1438-7492
Publisher
Wiley
Journal / Book Title
Macromolecular Materials and Engineering
Volume
303
Copyright Statement
© 2018 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim. This is the accepted version of the following article: W. Song, V. L. Tagarielli, K.‐Y. Lee, Macromol. Mater. Eng. 2018, 1800363., which has been published in final form at https://dx.doi.org/10.1002/mame.201800363
Subjects
Science & Technology
Technology
Physical Sciences
Materials Science, Multidisciplinary
Polymer Science
Materials Science
epoxy
macroporous polymers
mechanical properties
toughness and impact resistance
SYNTACTIC FOAM
FLEXURAL STRENGTH
RUBBER
DEFORMATION
MORPHOLOGY
POROSITY
03 Chemical Sciences
09 Engineering
Polymers
Publication Status
Published
Article Number
1800363
Date Publish Online
2018-09-24