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  4. Unravelling the optical responses of nanoplasmonic mirror-on-mirror metamaterials.
 
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Unravelling the optical responses of nanoplasmonic mirror-on-mirror metamaterials.
File(s)
Metal-on-metal-9_for PCCP_Draft2.doc (2.26 MB)
Accepted version
Author(s)
Sikdar, D
Hasan, SB
Urbakh, M
Edel, JB
Kornyshev, AA
Type
Journal Article
Abstract
Mirror-on-mirror platforms based on arrays of metallic nanoparticles, arranged top-down or self-assembled on a thin metallic film, have interesting optical properties. Interaction of localized surface-plasmons in nanoparticles with propagating surface-plasmons in the film underpins the exotic features of such platforms. Here, we present a comprehensive theoretical framework which emulates such a system using a five-layer-stack model and calculate its reflectance, transmittance, and absorbance spectra. The theory rests on dipolar quasi-static approximations incorporating image-forces and effective medium theory. Systematically tested against full-wave simulations, this simple approach proves to be adequate within its obvious applicability limits. It is used to study optical signals as a function of nanoparticle dimensions, interparticle separation, metal film thickness, the gap between the film and nanoparticles, and incident light characteristics. Several peculiar features are found, e.g., quenching of reflectivity in certain frequency domains or shift of the reflectivity spectra. Schemes are proposed to tailor those as functions of the mentioned parameters. Calculating the system's optical responses in seconds, as compared to much longer running simulations, this theory helps to momentarily unravel the role of each system parameter in light reflection, transmission, and absorption, facilitating thereby the design and optimisation of novel mirror-on-mirror systems.
Date Issued
2016-07-05
Date Acceptance
2016-06-30
Citation
Physical Chemistry Chemical Physics, 2016, 18, pp.20486-20498
URI
http://hdl.handle.net/10044/1/41560
DOI
https://www.dx.doi.org/10.1039/c6cp04551k
ISSN
1463-9084
Publisher
Royal Society of Chemistry
Start Page
20486
End Page
20498
Journal / Book Title
Physical Chemistry Chemical Physics
Volume
18
Copyright Statement
© the Owner Societies 2016
Subjects
Science & Technology
Physical Sciences
Chemistry, Physical
Physics, Atomic, Molecular & Chemical
Chemistry
Physics
Caged gold nanorods
Nanoparticle arrays
Metal nanoparticles
Plasmonic nanoparticle
Silver nanoparticle
Plasmene nanosheets
Shape
Size
Film
Interfaces
Chemical Physics
Chemical Sciences
Publication Status
Published
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