Heterotrimetallic complexes of iron and ruthenium based on vinyliminium dithiocarboxylate ligands
File(s)JOMC Wilton-Ely Multimetallic Fe2Ru AAC.pdf (1.86 MB)
Accepted version
Author(s)
Type
Journal Article
Abstract
The diiron vinyliminium compounds [Fe2{μ-η1:η3-C(R2) = C(H)C=N(Me)R1}(μ-CO)(CO)(Cp)2]OSO2CF3 (R1 = Xyl = 2,6-C6H3Me2, R2 = Me; R1 = Me, R2 = CO2Me) provide a versatile entry point for many subsequent transformations, such as their reaction with carbon disulfide to provide zwitterionic dithiocarboxylate products. These compounds react with the coordinatively-unsaturated ruthenium vinyl precursors [Ru(CH=CHR3)Cl(CO)(PPh3)2] (R3 = C6H4Me-4, 1-Pyrenyl) to yield heterotrimetallic Fe2Ru compounds, exhibiting vinyl moieties at both iron and ruthenium centres. The emission associated with the pyrenyl unit is enhanced in the diiron vinyliminium ruthenium pyrenyl complex compared to the diethyldithiocarbamate analogue.
Date Issued
2019-04-15
Date Acceptance
2019-02-01
Citation
Journal of Organometallic Chemistry, 2019, 886, pp.9-12
ISSN
0022-328X
Publisher
Elsevier
Start Page
9
End Page
12
Journal / Book Title
Journal of Organometallic Chemistry
Volume
886
Copyright Statement
© 2019 Elsevier B.V. All rights reserved. This manuscript is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International Licence http://creativecommons.org/licenses/by-nc-nd/4.0/
Sponsor
The Royal Society
Royal Society
Grant Number
NF160909
Subjects
0302 Inorganic Chemistry
0305 Organic Chemistry
0399 Other Chemical Sciences
Organic Chemistry
Publication Status
Published
Date Publish Online
2019-02-14