A study of the effect of aerosols on surface ozone through meteorology feedbacks over China
File(s)acp-21-5705-2021.pdf (4.76 MB)
Published version
Author(s)
Type
Journal Article
Abstract
Interactions between aerosols and gases in the atmosphere have been the focus of an increasing number of studies in recent years. Here, we focus on aerosol effects on tropospheric ozone that involve meteorological feedbacks induced by aerosol–radiation interactions. Specifically, we study the effects that involve aerosol influences on the transport of gaseous pollutants and on atmospheric moisture, both of which can impact ozone chemistry. For this purpose, we use the UK Earth System Model (UKESM1), with which we performed sensitivity simulations including and excluding the aerosol direct radiative effect (ADE) on atmospheric chemistry, and focused our analysis on an area with a high aerosol presence, namely China. By comparing the simulations, we found that ADE reduced shortwave radiation by 11 % in China and consequently led to lower turbulent kinetic energy, weaker horizontal winds and a shallower boundary layer (with a maximum of 102.28 m reduction in north China). On the one hand, the suppressed boundary layer limited the export and diffusion of pollutants and increased the concentration of CO, SO2, NO, NO2, PM2.5 and PM10 in the aerosol-rich regions. The NO/NO2 ratio generally increased and led to more ozone depletion. On the other hand, the boundary layer top acted as a barrier that trapped moisture at lower altitudes and reduced the moisture at higher altitudes (the specific humidity was reduced by 1.69 % at 1493 m on average in China). Due to reduced water vapour, fewer clouds were formed and more sunlight reached the surface, so the photolytical production of ozone increased. Under the combined effect of the two meteorology feedback methods, the annual average ozone concentration in China declined by 2.01 ppb (6.2 %), which was found to bring the model into closer agreement with surface ozone measurements from different parts of China.
Date Issued
2021-04-15
Date Acceptance
2021-03-04
Citation
Atmospheric Chemistry and Physics, 2021, 21 (7), pp.5705-5718
ISSN
1680-7316
Publisher
Copernicus Publications
Start Page
5705
End Page
5718
Journal / Book Title
Atmospheric Chemistry and Physics
Volume
21
Issue
7
Copyright Statement
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
License URL
Identifier
http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000641147800002&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=1ba7043ffcc86c417c072aa74d649202
Subjects
Science & Technology
Life Sciences & Biomedicine
Physical Sciences
Environmental Sciences
Meteorology & Atmospheric Sciences
Environmental Sciences & Ecology
ATMOSPHERIC BOUNDARY-LAYER
TROPOSPHERIC OZONE
PHOTOLYSIS RATES
ACCURATE SIMULATION
AIR-POLLUTION
MINERAL DUST
MODEL
IMPACT
PHOTOCHEMISTRY
IMPLEMENTATION
Publication Status
Published
Date Publish Online
2021-04-15