How observable Is lithium plating? Differential voltage analysis to identify and quantify lithium plating following fast charging of cold lithium-Ion batteries
File(s)J. Electrochem. Soc.-2019-Campbell-A725-39.pdf (2.38 MB)
Published version
OA Location
Author(s)
Campbell, Ian D
Marzook, Mohamed
Marinescu, Monica
Offer, Gregory J
Type
Journal Article
Abstract
Fast charging of batteries is currently limited, particularly at low temperatures, due to difficulties in understanding lithium plating. Accurate, online quantification of lithium plating increases safety, enables charging at speeds closer to the electrochemical limit and accelerates charge profile development. This work uses different cell cooling strategies to expose how voltage plateaus arising from cell self-heating and concentration gradients during fast charging can falsely indicate plating, contrary to prevalent current assumptions. A solution is provided using Differential Voltage (DV) analysis, which confirms that lithium stripping is observable. However, scanning electron microscopy and energy-dispersive X-ray analysis are used to demonstrate the inability of the plateau technique to detect plating under certain conditions. The work highlights error in conventional plating quantification that leads to the dangerous underestimation of plated amounts. A novel method of using voltage plateau end-point gradients is proposed to extend the sensitivity of the technique, enabling measurement of lower levels of lithium stripping and plating. The results are especially relevant to automotive OEMs and engineers wishing to expand their online and offline tools for fast charging algorithm development, charge management and state-of-health diagnostics.
Date Issued
2019-03-06
Date Acceptance
2019-03-01
Citation
Journal of The Electrochemical Society, 2019, 166 (4), pp.A725-A739
ISSN
0013-4651
Publisher
Electrochemical Society
Start Page
A725
End Page
A739
Journal / Book Title
Journal of The Electrochemical Society
Volume
166
Issue
4
Copyright Statement
© The Author(s) 2019. Published by ECS. This is an open access article distributed under the terms of the Creative Commons Attribution 4.0 License (CC BY, http://creativecommons.org/licenses/by/4.0/), which permits unrestricted reuse of the work in any medium, provided the original work is properly cited.
Identifier
http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000460499200002&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=1ba7043ffcc86c417c072aa74d649202
Subjects
Science & Technology
Physical Sciences
Technology
Electrochemistry
Materials Science, Coatings & Films
Materials Science
CELLS
GRAPHITE
PERFORMANCE
QUANTIFICATION
ELECTRODE
SAFETY
TIME
Publication Status
Published
Date Publish Online
2019-03-06