Total Synthesis of (+)-Lophirone H and Its pentamethyl ether utilizing an oxonium-prins cyclization

File(s)

Supporting Information Lophirone H FINAL CORRECTED Mk2.pdf (4.42 MB)

Supporting information

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Total Synthesis of Lophirone H - Org Lett FINAL CORRECTED Mk2.docx (2.42 MB)

Accepted version

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Author(s)

Abas, H

Linsdall, SM

Mamboury, M

Rzepa, HS

Spivey, AC

Type

Journal Article

Abstract

The first total synthesis of (+)-lophirone H (1) and its pentamethyl ether 29, featuring an oxonium–Prins cyclization/benzylic cation trapping reaction, is described.

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Date Issued

2017-05-19

Date Acceptance

2017-03-02

Citation

Organic Letters, 2017, 19 (10), pp.2486-2489

URI

http://hdl.handle.net/10044/1/49291

DOI

https://www.dx.doi.org/10.1021/acs.orglett.7b00642

ISSN

1523-7052

Publisher

American Chemical Society

Start Page

2486

End Page

2489

Journal / Book Title

Organic Letters

Volume

19

Issue

10

Copyright Statement

© 2017 American Chemical Society.

Identifier

http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000402023500007&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=1ba7043ffcc86c417c072aa74d649202

Subjects

Science & Technology

Physical Sciences

Chemistry, Organic

Chemistry

LOPHIRA-LANCEOLATA

STEREOSELECTIVE-SYNTHESIS

OXIDATIVE STRESS

CHALCONE DIMERS

BIFLAVONOIDS

OXAZOLIDIN-2-ONES

TETRAHYDROFURANS

PTEROCARPANS

POLYPHENOLS

DERIVATIVES

Publication Status

Published