V2O5 as magnesium cathode material with extended cyclic stability
File(s)
Published version
Author(s)
Drosos, Charalampos
Moss, Benjamin
Kafizas, Andreas
Vernardou, Dimitra
Type
Journal Article
Abstract
In this work, the electrochemical performance of aerosol-assisted chemical vapour deposited
vanadium pentoxide cathodes at 600 °C, is presented. The as-grown oxides indicate specific
discharge capacity of 300 mA h g-1 with capacity retention of 92 % after 10000 scans,
coulombic efficiency of 100 %, noble structural stability and high reversibility. The present
study shows the possibility to grow large-area magnesium cathode material with extended
cycle stability via utilization of an aqueous electrolyte under a corrosive environment. This
enhanced performance may be a combination of electrode morphology and adherence, when
compared to previous work employing electrode growth temperature at 500 °C.
vanadium pentoxide cathodes at 600 °C, is presented. The as-grown oxides indicate specific
discharge capacity of 300 mA h g-1 with capacity retention of 92 % after 10000 scans,
coulombic efficiency of 100 %, noble structural stability and high reversibility. The present
study shows the possibility to grow large-area magnesium cathode material with extended
cycle stability via utilization of an aqueous electrolyte under a corrosive environment. This
enhanced performance may be a combination of electrode morphology and adherence, when
compared to previous work employing electrode growth temperature at 500 °C.
Date Issued
2020-02-22
Date Acceptance
2020-02-22
Citation
Journal of Electrochemical Science and Engineering, 2020, 10 (3), pp.257-262
ISSN
1847-9286
Publisher
International Association of Physical Chemists (IAPC)
Start Page
257
End Page
262
Journal / Book Title
Journal of Electrochemical Science and Engineering
Volume
10
Issue
3
Copyright Statement
©2020 by the authors; licensee IAPC, Zagreb, Croatia. This article is an open-access article
distributed under the terms and conditions of the Creative Commons Attribution license
(http://creativecommons. org/licenses/by/4.0/)
distributed under the terms and conditions of the Creative Commons Attribution license
(http://creativecommons. org/licenses/by/4.0/)
Sponsor
The Royal Society
Identifier
http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000535684200003&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=1ba7043ffcc86c417c072aa74d649202
Grant Number
RSG\R1\180434
Subjects
Science & Technology
Physical Sciences
Electrochemistry
Magnesium ion batteries
chemical vapor deposition
electrode morphology
coating adherence
corrosive environment
ION
BATTERIES
ELECTRODE
OXIDE
Publication Status
Published
Date Publish Online
2020-02-22