We present X-ray absorption measurements near the K-edge of laser heated aluminum in a pump-probe configuration using X-rays generated in a laser wakefield accelerator. A 30 fs duration laser pulse from the Herculeslaser system was split into two beamlines, with one used to heat a 4 µm thickness Al foil and the second to drive a laser wakefield accelerator. The laser-heated plasma was probed at various pump-probe delays using the femtosecond duration X-rays generated by betatron oscillations of the electrons in the wakefield. We observe an apparent blue-shift of the K-edge occurring on a sub-picosecond timescale in the transmission spectra.