Practical dissolution dynamic nuclear polarization
File(s)
Accepted version
OA Location
Author(s)
Type
Journal Article
Abstract
This review article intends to provide insightful advice for dissolution-dynamic nuclear polarization in the form of a practical handbook. The goal is to aid research groups to effectively perform such experiments in their own laboratories. Previous review articles on this subject have covered a large number of useful topics including instrumentation, experimentation, theory, etc. The topics to be addressed here will include tips for sample preparation and for checking sample health; a checklist to correctly diagnose system faults and perform general maintenance; the necessary mechanical requirements regarding sample dissolution; and aids for accurate, fast and reliable polarization quantification. Herein, the challenges and limitations of each stage of a typical dissolution-dynamic nuclear polarization experiment are presented, with the focus being on how to quickly and simply overcome some of the limitations often encountered in the laboratory.
Date Issued
2021-10-01
Date Acceptance
2021-04-09
Citation
Progress in Nuclear Magnetic Resonance Spectroscopy, 2021, 126-127, pp.59-100
ISSN
0079-6565
Publisher
Elsevier
Start Page
59
End Page
100
Journal / Book Title
Progress in Nuclear Magnetic Resonance Spectroscopy
Volume
126-127
Copyright Statement
© 2021 Elsevier B.V. All rights reserved. This manuscript version is made available under the CC-BY-NC-ND 4.0 license https://creativecommons.org/licenses/by-nc-nd/4.0/
Identifier
https://www.ncbi.nlm.nih.gov/pubmed/34852925
PII: S0079-6565(21)00015-7
Subjects
BRUTE-FORCE
Chemistry
Chemistry, Physical
CP
CROSS-POLARIZATION
dDNP
DNP
ENHANCED NMR
HIGH-RESOLUTION NMR
Hyperpolarization
LONG-LIVED STATES
MAGNETIC-RESONANCE
MULTIDIMENSIONAL NMR
NMR
Physical Sciences
Physics
Physics, Atomic, Molecular & Chemical
Polarization quantification
Sample preparation
Science & Technology
SOLID EFFECT DNP
Spectroscopy
SPIN-LATTICE RELAXATION
SPY-NMR
Systems maintenance
Technology
Transport dynamics
ULTRAFAST 2D NMR
Publication Status
Published
Coverage Spatial
England
Date Publish Online
2021-05-21