On the origin and application of the Bruggeman correlation for analysing transport phenomena in electrochemical systems
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Published version
Author(s)
Tjaden, B
Cooper, SJ
Brett, DJL
Kramer, D
Shearing, PR
Type
Journal Article
Abstract
The widely used Bruggeman equations correlate tortuosity factors of porous media with their porosity. Finding diverse application from optics to bubble formation, it received considerable attention in fuel cell and battery research, recently. The ability to estimate tortuous mass transport resistance based on porosity alone is attractive, because direct access to the tortuosity factors is notoriously difficult. The correlation, however, has limitations, which are not widely appreciated owing to the limited accessibility of the original manuscript. We retrace Bruggeman's derivation, together with its initial assumptions, and comment on validity and limitations apparent from the original work to offer some guidance on its use.
Date Issued
2016-05-01
Date Acceptance
2016-03-01
Citation
Current Opinion in Chemical Engineering, 2016, 12 (1), pp.44-51
ISSN
2211-3398
Publisher
Elsevier
Start Page
44
End Page
51
Journal / Book Title
Current Opinion in Chemical Engineering
Volume
12
Issue
1
Copyright Statement
© 2016 The Authors. This is an
open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).
open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).
License URL
Sponsor
Engineering & Physical Science Research Council (EPSRC)
Identifier
https://www.sciencedirect.com/science/article/pii/S2211339816300119
Grant Number
EP/J003085/1
Subjects
Science & Technology
Life Sciences & Biomedicine
Technology
Biotechnology & Applied Microbiology
Engineering, Chemical
Engineering
CONDUCTIVITY
TORTUOSITY
DIFFUSION
0904 Chemical Engineering
Publication Status
Published
Date Publish Online
2016-03-12