Effects of bismuth on the microstructure and crack propagation in Sn–Ag–Cu-Bi solder joints during thermal cycling
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Published version
Author(s)
Hsieh, CL
Coyle, RJ
Belyakov, SA
Xian, JW
Gourlay, CM
Type
Journal Article
Abstract
Bismuth is added to Sn–Ag–Cu-based solders to increase strength and solder joint reliability but accelerated thermal cycling (ATC) tests have shown variable thermal fatigue performance. To better understand their thermal fatigue mechanisms, we investigate three Sn–Ag–Cu-Bi solder alloys containing between 3 and 6 wt.% bismuth in two types of ball grid array (BGA) packages tested using a harsh ATC profile of -55/125 °C. We study how the bismuth additions affect the microstructure after soldering, after ~ 4 years storage at room temperature and after thermal cycling. The Weibull reliability statistics are then correlated with the microstructural evolution including solutionising, homogenisation, bismuth precipitation, recrystallisation and crack paths. The results show that high strength Sn–Ag–Cu-Bi solders can improve the resistance to thermal fatigue, but high solder strength needs to be balanced against excessive stress transfer to the intermetallic attachment layer.
Date Issued
2025-10-01
Date Acceptance
2025-10-08
Citation
Journal of Materials Science: Materials in Electronics, 2025, 36 (30)
ISSN
0957-4522
Publisher
Springer Science and Business Media LLC
Journal / Book Title
Journal of Materials Science: Materials in Electronics
Volume
36
Issue
30
Copyright Statement
© The Author(s), 2025 Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.
License URL
Publication Status
Published
Article Number
1926
Date Publish Online
2025-10-24