Isolation of an unusual [Cu-6] nanocluster through sequential addition of copper(I) to a polynucleating ligand
File(s)Cu6_14thJan.pdf (1.39 MB)
Accepted version
Author(s)
Phanopoulos, A
Warren, M
White, AJP
Horton, A
Crimmin, MR
Type
Journal Article
Abstract
Addition of 2 equiv. of CuI to a [Cu]4 multimetallic complex results in cluster formation leading to the isolation of a rare bicapped tetrahedral [Cu6I2] cluster that is stabilised by two conformationally constrained polynucleating ligands.
Date Issued
2017-01-20
Date Acceptance
2017-01-20
Citation
Dalton Transactions: an international journal of inorganic chemistry, 2017, 46 (7), pp.2077-2080
ISSN
1477-9226
Publisher
Royal Society of Chemistry
Start Page
2077
End Page
2080
Journal / Book Title
Dalton Transactions: an international journal of inorganic chemistry
Volume
46
Issue
7
Copyright Statement
© 2017 Royal Society of Chemistry.
Sponsor
Shell Global Solutions International BV
Identifier
http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000395864200004&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=1ba7043ffcc86c417c072aa74d649202
Grant Number
PO No. 4550119140
Subjects
Science & Technology
Physical Sciences
Chemistry, Inorganic & Nuclear
Chemistry
COORDINATION POLYMERS
NEUTRON-DIFFRACTION
CLUSTERS
COMPLEXES
HYDRIDE
REACTIVITY
MODULATION
ACTIVATION
DIOXYGEN
CORE
Publication Status
Published
Date Publish Online
2017-01-20