Sub-picosecond permittivity of carbon nitrides probed with terahertz spectroscopy: revealing high dielectric response and conductivity
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Published online version
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Author(s)
Type
Journal Article
Abstract
Organic based semiconductor materials offer emerging and sustainable solutions for solar energy conversion technologies and electronics. However, knowledge of their intrinsic (photo)physical properties is often limited, especially the effect of dielectric properties (εr = ε′) on exciton separation and charge generation at sub-picosecond timescales, which corresponds to THz frequencies. Thus, THz Time Domain Spectroscopy (THz-TDS) is used to directly and accurately extract the complex permittivity (ε = ε′ + iε″) and THz conductivity (σTHz) of organic Carbon Nitrides (CNx) and other polymers and elucidate the influence of environmental humidities. Overall, the THz dielectric response ε′ of CNx surpasses other organic and even glycolated materials, and water. For the ionic and 2D carbon nitride K-PHI, complex permittivity ε was observed to be strongly humidity dependent, with both ε′ and σTHz doubling from dry to humid conditions (ε′ from ∼4 to 8, σTHz 75 to 150 S/m, respectively). When compared to other photocatalysts, the THz dielectric response of CNx and especially humid K-PHI is within range of well-known oxides such as TiO2 that can efficiently generate charges from excitons, due to low exciton binding energies resulting from high ε′. The importance of dielectric property characterization on functionally relevant frequencies is thus highlighted, especially in the THz gap (0.1 – 10 THz), to understand the photophysical behaviour of organic semiconductors, even in the presence of water and hydrated ions. Such THz complex permittivity determination may also be beneficial for exploring next generation photo(electro)catalysts, electronics or ionotronics, and for computational property predictions that often require knowledge of ultrafast photophysical properties.
Date Issued
2026-04-01
Date Acceptance
2026-02-03
Citation
EES Solar, 2026, 2 (2), pp.338-350
ISSN
3033-4063
Publisher
Royal Society of Chemistry
Start Page
338
End Page
350
Journal / Book Title
EES Solar
Volume
2
Issue
2
Copyright Statement
© 2026 The Author(s). Published by the Royal Society of Chemistry Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
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Publication Status
Published
Date Publish Online
2026-02-06