Fast near-infrared photodetectors based on nontoxic and solution-processable AgBiS2
Author(s)
Type
Journal Article
Abstract
Solution-processable near-infrared (NIR) photodetectors are urgently needed for a wide range of next-generation electronics, including sensors, optical communications and bioimaging. However, it is rare to find photodetectors with >300 kHz cut-off frequencies, especially in the NIR region, and many of the emerging inorganic materials explored are comprised of toxic elements, such as lead. Herein, solution-processed AgBiS2 photodetectors with high cut-off frequencies under both white light (>1 MHz) and NIR (approaching 500 kHz) illumination are developed. These high cut-off frequencies are due to the short transit distances of charge-carriers in the ultrathin photoactive layer of AgBiS2 photodetectors, which arise from the strong light absorption of this material, such that film thicknesses well below 120 nm are sufficient to absorb >65% of NIR to visible light. It is also revealed that ion migration plays a critical role in the photo-response speed of these devices, and its detrimental effects can be mitigated by finely tuning the thickness of the photoactive layer, which is important for achieving low dark current densities as well. These outstanding characteristics enable the realization of air-stable, real-time heartbeat sensors based on NIR AgBiS2 photodetectors, which strongly motivates their future integration in high-throughput systems.
Date Issued
2024-05
Date Acceptance
2023-11-17
Citation
Small, 2024, 20 (18)
ISSN
1613-6810
Publisher
Wiley
Journal / Book Title
Small
Volume
20
Issue
18
Copyright Statement
© 2023 The Authors. Small published by Wiley-VCH GmbH
This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
License URL
Identifier
https://onlinelibrary.wiley.com/doi/full/10.1002/smll.202310199
Subjects
AgBiS2
Chemistry
Chemistry, Multidisciplinary
Chemistry, Physical
cut-off frequency
EFFICIENCY
heart-beat sensors
IONIC TRANSPORT
Materials Science
Materials Science, Multidisciplinary
Nanoscience & Nanotechnology
near-infrared photodetectors
PEROVSKITE
Physical Sciences
Physics
Physics, Applied
Physics, Condensed Matter
Science & Technology
Science & Technology - Other Topics
solution-processable electronics
Technology
ultrathin absorbers
Publication Status
Published
Article Number
2310199
Date Publish Online
2023-12-08