Fluorene copolymer bilayers for emission colour tuning in inverted hybrid light emitting diodes
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Author(s)
Faria, JCD
Campbell, AJ
McLachlan, MA
Type
Journal Article
Abstract
We present a robust, entirely solution-based processing route for the deposition of planar F8BT/TFB poly(9,9-dioctylfluorene-alt-benzothiadiazole)/poly(9,9-dioctylfluorene-alt-N-(4-butylphenyl)-diphenylamine) emissive/hole transport bilayers for emission colour tuning in inverted organic–inorganic hybrid light emitting diodes (HyLEDs). Our method allows the facile exploration of TFB thickness for the first time within inverted devices; here we describe the influence of TFB thickness on the device performance. In particular, we demonstrate significant variations in device electroluminescence with highly controlled tunability between green and orange (550 to 610 nm) emission; correlating directly with the thickness of the TFB layer. These changes are in parallel with a 20-fold increase in current efficiency with respect to F8BT-only devices, with our bilayer devices exhibiting luminance values exceeding 11 000 cd m−2. Additionally, through reflectance and angle-dependent electroluminescence measurements we explore the presence of microcavity effects and their impact on device behaviour. We introduce TFB not only as a charge blocking/transporting layer but also as an optical emission-tuning layer.
Date Issued
2015-04-16
Date Acceptance
2015-04-14
Citation
Journal of Materials Chemistry C, 2015, 3 (19), pp.4945-4953
ISSN
2050-7534
Publisher
Royal Society of Chemistry
Start Page
4945
End Page
4953
Journal / Book Title
Journal of Materials Chemistry C
Volume
3
Issue
19
Copyright Statement
This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
License URL
Sponsor
Engineering and Physical Sciences Research Council
Grant Number
EP/G037515/1
Publication Status
Published