Mean-field theory of electrical double layer in ionic liquids with account of short-range correlations
File(s)LCL_EA.pdf (478.67 KB)
Accepted version
Author(s)
Goodwin, ZAH
Feng, G
Kornyshev, AA
Type
Journal Article
Abstract
We develop the theory of the electrical double layer in ionic liquids as proposed earlier by Kornyshev (2007). In the free energy function we keep the so called ‘short-range correlation terms’ which were omitted there. With some simplifying assumptions, we arrive at a modified expression for differential capacitance, which makes differential capacitance curves less sharply depending on electrode potential and having smaller values at extrema than in the previous theory. This brings the results closer to typical experimental observations, and makes it appealing to use this formalism for treatment of experimental data. Implications on Debye length and the extent of ion paring in ionic liquids are then briefly discussed.
Date Issued
2016-12-21
Date Acceptance
2016-12-13
Citation
Electrochimica Acta, 2016, 225, pp.190-197
ISSN
0013-4686
Publisher
Elsevier
Start Page
190
End Page
197
Journal / Book Title
Electrochimica Acta
Volume
225
Copyright Statement
© 2016 Elsevier Ltd. All rights reserved. This manuscript is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International http://creativecommons.org/licenses/by-nc-nd/4.0/
Identifier
http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000393502500021&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=1ba7043ffcc86c417c072aa74d649202
Subjects
Science & Technology
Physical Sciences
Electrochemistry
Ionic liquids
Double layer
short-range correlations
ion pairing
DIFFERENTIAL CAPACITANCE
GRAPHITE-ELECTRODES
HYDRATION FORCES
MOLTEN-SALT
ELECTROCHEMICAL INTERFACES
SOLVATION FORCES
MODEL
SURFACE
ELECTROLYTES
CARBON
Publication Status
Published