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Amine-modified polyionic liquid supports enhance the efficacy of PdNPs for the catalytic hydrogenation of CO₂ to formate
File(s)
d3cc04987f.pdf (729.16 KB)
Published version
Author(s)
Paterson, Reece
Fahy, Luke E
Arca, Elisabetta
Dixon, Casey
Wills, Corinne Y
Type
Journal Article
Abstract
Palladium nanoparticles stabilised by aniline modified polymer immobilised ionic liquid is a remarkably active catalyst for the hydrogenation of CO2 to formate; the initial TOF of 500 h-1 is markedly higher than either unmodified catalyst or its benzylamine and N,N-dimethylaniline modified counterparts and is among the highest to be reported for a PdNP-based catalyst.
Date Issued
2023-11-21
Date Acceptance
2023-10-17
Citation
Chemical Communications, 2023, 59 (90), pp.13470-13473
URI
URL
DOI
ISSN
1359-7345
Publisher
Royal Society of Chemistry
Start Page
13470
End Page
13473
Journal / Book Title
Chemical Communications
Volume
59
Issue
90
Copyright Statement
© The Royal Society of Chemistry 2023 Open Access Article This article is licensed under a Creative Commons Attribution 3.0 Unported Licence
License URL
Identifier
https://www.ncbi.nlm.nih.gov/pubmed/37877311
Publication Status
Published
Coverage Spatial
England
Date Publish Online
2023-10-23