The role of competing magnetic interactions on the abnormal expansion properties in manganese antiperovskites, Mn(3+x)A(1-x)N (A = Ni, Sn)
File(s)MnAN-JAC-referee-changes-final.pdf (1.32 MB)
Accepted version
Author(s)
Boldrin, D
Cohen, LF
Type
Journal Article
Abstract
The role of competing magnetic interactions in Mn-doped manganese antiperovskites Mn3+xA1−xN (A = Ni and Sn) has been explored using magnetometry and dilatometry, with particular focus on their relation to abnormal expansion properties. Rare negative magnetisation phenomena are found in zero-field-cooled conditions for both A = Sn and Ni when Mn is doped on the A site. Such behaviour is evidence of both competing magnetic sublattices and magnetocrystalline anisotropy. By comparison with other compounds with the antiferromagnetic magnetic structure, we suggest that competing interactions along with magnetovolume coupling influence the near-zero thermal expansion behaviour at intermediate temperatures below in the A = Ni family.
Date Issued
2017-03-30
Date Acceptance
2016-12-20
Citation
Journal of Alloys and Compounds, 2017, 699, pp.887-891
ISSN
0925-8388
Publisher
Elsevier
Start Page
887
End Page
891
Journal / Book Title
Journal of Alloys and Compounds
Volume
699
Copyright Statement
© 2017 Elsevier Ltd. All rights reserved. This manuscript is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International Licence http://creativecommons.org/licenses/by-nc-nd/4.0/
Sponsor
Engineering & Physical Science Research Council (EPSRC)
Engineering & Physical Science Research Council (EPSRC)
Imperial College Trust
Engineering & Physical Science Research Council (E
Identifier
http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000393727500123&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=1ba7043ffcc86c417c072aa74d649202
Grant Number
EP/E016243/1
EP/G060940/1
PHES_P43111
EP/K503733/1
Subjects
Science & Technology
Physical Sciences
Technology
Chemistry, Physical
Materials Science, Multidisciplinary
Metallurgy & Metallurgical Engineering
Chemistry
Materials Science
Magneto-volume effects
Nitride materials
Magnetically ordered materials
THERMAL-EXPANSION
BEHAVIOR
MN4N
Publication Status
Published
Date Publish Online
2016-12-24