Meyer-Schuster rearrangement of propargylic alcohols mediated by phosphorus-containing Brønsted acid catalysts
File(s)
Published version
Author(s)
Radtanajiravong, Lalita
Peters, Jake
Hummell, Jake
Diez-Gonzalez, Silvia
Type
Journal Article
Abstract
Commercially available (aqueous) hypophosphorus acid is an efficient catalyst for the synthesis of ,-unsaturated carbonyl compounds from their corresponding propargylic alcohols. Reactions were carried out in technical toluene in the presence of air and in several instances the desired products were isolated analytically pure after a simple work-up.
Date Issued
2022-08-31
Date Acceptance
2022-08-31
Citation
Organic and Biomolecular Chemistry, 2022, 36 (20), pp.7338-7342
ISSN
1477-0520
Publisher
Royal Society of Chemistry
Start Page
7338
End Page
7342
Journal / Book Title
Organic and Biomolecular Chemistry
Volume
36
Issue
20
Copyright Statement
© The Royal Society of Chemistry 2022. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
License URL
Identifier
https://pubs.rsc.org/en/content/articlelanding/2022/OB/D2OB01259F
Subjects
Science & Technology
Physical Sciences
Chemistry, Organic
Chemistry
HYPOPHOSPHOROUS ACID
Organic Chemistry
0304 Medicinal and Biomolecular Chemistry
0305 Organic Chemistry
Publication Status
Published
Date Publish Online
2022-08-31