The role of microparticles on the shape and surface tension of static bubbles
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Published version
OA Location
Author(s)
Wang, H
Brito-Parada, PR
Type
Journal Article
Abstract
HYPOTHESIS: Surface tension is a critical parameter in bubbles and foams, yet it is difficult to assess when microparticles are attached at the interface. By considering the interaction force between an air-liquid interface and microparticles, modified equations for sessile bubble tensiometry can be derived to determine the surface tension and shape of static microparticle-laden bubbles. EXPERIMENTS: A modified sessile bubble method, in which the forces between microparticles and the air-liquid interface are considered, was developed and used to analyse the surface tension of bubbles fully coated by a monolayer of silica microparticles of different sizes. The results are compared to those obtained using classical sessile bubble tensiometry. The new method is also used to investigate the contours of particle-laden bubbles of varying particle radius and contact angle. FINDINGS: While the classical sessile bubble method overestimates the surface tension, results obtained using the modified sessile bubble method show that the surface tension of static microparticle-laden bubbles remains the same as that of uncoated bubbles, with no dependency on the particle size. The discrepancy is due to the fact that microparticles attached to the air-liquid interface deform a bubble in a similar way that changes in surface tension do for uncoated bubbles.
Date Issued
2020-11-30
Date Acceptance
2020-11-24
Citation
Journal of Colloid and Interface Science, 2020, 587, pp.14-23
ISSN
0021-9797
Publisher
Elsevier
Start Page
14
End Page
23
Journal / Book Title
Journal of Colloid and Interface Science
Volume
587
Copyright Statement
Copyright 2020 The Authors. Published by Elsevier Inc.This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
Sponsor
Commission of the European Communities
Identifier
https://www.ncbi.nlm.nih.gov/pubmed/33360886
PII: S0021-9797(20)31613-1
Grant Number
821265
Subjects
Bubble shape
Particle-bubble interaction force
Particle-laden bubble
Sessile bubble method
Surface tension
Publication Status
Published online
Coverage Spatial
United States
Date Publish Online
2020-11-30