Abrupt onset of the capillary-wave spectrum at wall-fluid interfaces
File(s)DimRed.pdf (390.11 KB)
Accepted version
Author(s)
Parry, Andrew
rascon, carlos
Type
Journal Article
Abstract
Surfaces between 3D solids and fluids exhibit a wide variety of phenomena both at equilibrium,
such as roughening transitions, interfacial fluctuations and wetting, and also out-of-equilibrium, such
as the surface growth of driven interfaces. These phenomena are described very successfully using
lower dimensional (2D) effective models which focus on the physics associated with emergent mesoscopic lengths scales, parallel to the interface, where the 2D-like behaviour is physically transparent.
However, the precise conditions under which this dimensional reduction is justifiable have remained
unclear. Here we show that, for a wall-fluid interface, a dimensional reduction from 3D-like to 2D-like
behaviour – identified via the decay of density correlations – occurs abruptly at a specific value of the
contact angle, and indicates the beginning of interfacial-like 2D behaviour and the spontaneous onset
of the capillary-wave spectrum. The reduction from 3D to 2D is characterised by the divergence of
a correlation length perpendicular to the interface revealing a morphological change in the nature of
density correlations. Counter-intuitive effects occur, including that 3D behaviour can persist up to
the wetting temperature and also that 2D behaviour can begin when no wetting layer is present and
the adsorption is negative.
such as roughening transitions, interfacial fluctuations and wetting, and also out-of-equilibrium, such
as the surface growth of driven interfaces. These phenomena are described very successfully using
lower dimensional (2D) effective models which focus on the physics associated with emergent mesoscopic lengths scales, parallel to the interface, where the 2D-like behaviour is physically transparent.
However, the precise conditions under which this dimensional reduction is justifiable have remained
unclear. Here we show that, for a wall-fluid interface, a dimensional reduction from 3D-like to 2D-like
behaviour – identified via the decay of density correlations – occurs abruptly at a specific value of the
contact angle, and indicates the beginning of interfacial-like 2D behaviour and the spontaneous onset
of the capillary-wave spectrum. The reduction from 3D to 2D is characterised by the divergence of
a correlation length perpendicular to the interface revealing a morphological change in the nature of
density correlations. Counter-intuitive effects occur, including that 3D behaviour can persist up to
the wetting temperature and also that 2D behaviour can begin when no wetting layer is present and
the adsorption is negative.
Date Issued
2023-08-14
Date Acceptance
2023-07-17
Citation
Soft Matter, 2023, 19 (30), pp.5668-5673
ISSN
1744-683X
Publisher
Royal Society of Chemistry
Start Page
5668
End Page
5673
Journal / Book Title
Soft Matter
Volume
19
Issue
30
Copyright Statement
This journal is © The Royal Society of Chemistry 2023
Identifier
https://pubs.rsc.org/en/content/articlelanding/2023/sm/d3sm00761h
Publication Status
Published
Date Publish Online
2023-07-18