Ternary organic photodetectors based on pseudo–binaries nonfullerene–based acceptors
File(s)Zhang_2021_J._Phys._Mater._4_045001.pdf (1.53 MB)
Published version
Author(s)
Type
Journal Article
Abstract
The addition of a third component to a donor:acceptor blend is a powerful tool to enhance the power conversion efficiency of organic solar cells. Featuring a similar operating mechanism, organic photodetectors are also expected to benefit from this approach. Here, we fabricated ternary organic photodetectors, based on a polymer donor and two nonfullerene acceptors, resulting in a low dark current of 0.42 nA cm−2 at −2 V and a broadband specific detectivity of 1012 Jones. We found that exciton recombination in the binary blend is reduced in ternary devices due to the formation of a pseudo-binary microstructure with mixed donor–acceptor phases. With this approach a wide range of intermediate open-circuit voltages is accessible, without sacrificing light-to-current conversion. This results in ternary organic photodetector (TOPD) with improved Responsivity values in the near-infrared. Moreover, morphology analyses reveal that TOPD devices showed improved microstructure ordering and consequentially higher charge carrier mobilities compared to the reference devices.
Date Issued
2021-06-29
Date Acceptance
2021-06-16
Citation
Journal of Physics: Materials, 2021, 4 (4), pp.1-8
ISSN
2515-7639
Publisher
IOP Publishing
Start Page
1
End Page
8
Journal / Book Title
Journal of Physics: Materials
Volume
4
Issue
4
Copyright Statement
© 2021 The Author(s). Published by IOP Publishing Ltd. Original content from this work may be used under the terms of the Creative Commons Attribution 4.0 license. Any further distribution of this work must maintain attribution to the author(s) and the title of the work, journal citation and DOI.
License URL
Identifier
https://iopscience.iop.org/article/10.1088/2515-7639/ac0c0a
Date Publish Online
2021-06-29