Diffusion in nanoporous materials with special consideration of the measurement of determining parameters (IUPAC Technical Report)
File(s)10.1515_pac-2023-1126.pdf (9.07 MB)
Published version
Author(s)
Type
Journal Article
Abstract
The random motion (the diffusion) of guest molecules in nanoporous host materials is key to their manifold technological applications and, simultaneously, a ubiquitous phenomenon in nature quite in general. Based on a specification of the different conditions under which molecular diffusion in nanoporous materials may occur and of the thus resulting relevant parameters, a survey of the various ways of the measurement of the determining parameters is given. Starting with a condensed introduction to the respective measuring principles, the survey notably includes a summary of the various parameters accessible by each individual technique, jointly with an overview of their strengths and weaknesses as well as of the respective ranges of observation. The presentation is complemented by basic relations of diffusion theory and molecular modeling in nanoporous materials, illustrating their significance for enhancing the informative value of each measuring technique and the added value attainable by their combination. By providing guidelines for the measurement and reporting of diffusion properties of chemical compounds in nanopores, the document aims to contribute to the clarification and standardization of the presentation, nomenclature, and methodology associated with the documentation of diffusion phenomena in nanoporous materials serving for catalytic, mass separation, and other relevant purposes.
Date Issued
2025-01-29
Date Acceptance
2024-07-31
Citation
Pure and Applied Chemistry, 2025, 97 (1), pp.1-89
ISSN
0033-4545
Publisher
De Gruyter
Start Page
1
End Page
89
Journal / Book Title
Pure and Applied Chemistry
Volume
97
Issue
1
Copyright Statement
© 2024 IUPAC & De Gruyter. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International
License.
License.
Identifier
https://www.degruyter.com/document/doi/10.1515/pac-2023-1126/html
Subjects
Chemistry
Chemistry, Multidisciplinary
ELASTIC NEUTRON-SCATTERING
FRACTAL SURFACE-ROUGHNESS
FREQUENCY-RESPONSE METHOD
MAS PFG NMR
Mass transfer
MFI-TYPE ZEOLITES
nanostructured materials
NUCLEAR-MAGNETIC-RESONANCE
physical and biophysical chemistry division
Physical Sciences
PRESSURE SWING ADSORPTION
Science & Technology
SINGLE-MOLECULE
TRANSIENT CONCENTRATION PROFILES
TRANSITION-STATE THEORY
Publication Status
Published
Date Publish Online
2024-11-20