Landau theory-based relaxational modelling of first-order magnetic transition dynamics in magnetocaloric materials
File(s)Costa_2023_J._Phys._D__Appl._Phys._56_155001.pdf (1.88 MB)
Published version
Author(s)
Cohen, Lesley
Type
Journal Article
Abstract
The magnetocaloric effect is often largest within the neighborhood of a first-order phase transition. This effect can be utilized in magnetocaloric refrigeration, which completely eliminates the need for the greenhouse gases utilized in conventional refrigeration. However, such transitions present unique dynamical effects and are accompanied by hysteresis, which can be detrimental for such refrigeration applications. In this work, a Landau theory-based relaxational model is used to study the magnetic hysteresis and dynamics of the first-order magnetic transition of LaFe13−xSix. Fitting the experimental magnetization data as a function of applied magnetic field under different field sweep rates with this model provided the Landau parameters (A, B, and C) and the kinetic coefficient of the studied material. We demonstrate the tendency of the magnetic hysteresis to increase with the magnetic field sweep rate, underlining the importance of studying and minimizing the magnetic hysteresis in magnetic refrigerants at practical field sweep rates. While evaluating the temperature dependence of the time required for a complete transition to occur, a nonmonotonic behavior and a sharp peak were found for temperatures near the transition temperature. Such peaks occur at the same temperature as the peak of the magnetic entropy change for low fields, whereas for higher fields the two peaks decouple. This information is critical for technological applications (such as refrigerators/heat pumps) as it provides guidelines for the optimization of the magnetic field amplitude in order to reduce the transition timescale and consequently maximize the machine operational frequency and amount of heat that is pumped in/out per second.
Date Issued
2023-04-13
Date Acceptance
2023-02-10
Citation
Journal of Physics D: Applied Physics, 2023, 56 (15), pp.1-9
ISSN
0022-3727
Publisher
IOP Publishing
Start Page
1
End Page
9
Journal / Book Title
Journal of Physics D: Applied Physics
Volume
56
Issue
15
Copyright Statement
© 2023 The Author(s). Published by IOP Publishing Ltd. Original content from this work may be used under the terms of the Creative Commons Attribution 4.0 license. Any further distribution of this work must maintain attribution to the author(s) and the title of the work, journal citation and DOI.
License URL
Sponsor
Engineering and Physical Sciences Research Council
UK Research and Innovation
The Chancellor, Masters and Scholars of the Unive
Identifier
https://iopscience.iop.org/article/10.1088/1361-6463/acbe4e
Grant Number
EP/P030548/1
32645
EP/V042262/1
Subjects
02 Physical Sciences
09 Engineering
Applied Physics
Publication Status
Published
Article Number
155001
Date Publish Online
2023-03-13