Stereoselective reactions of ortho-quinone methide and ortho-quinone methide imines and their utility in natural product synthesis
File(s)oQM_oQMI_review_FINAL.docx (1.45 MB)
Accepted version
Author(s)
Nielsen, Christian D-T
Abas, Hossay
Spivey, Alan C
Type
Journal Article
Abstract
Herein presented is a review of the reactivity and synthetic utility of ortho-quinone methides and ortho-quinone methide imines. These versatile intermediates have received significant attention in the literature and new methods for their preparation and reaction as well as recent applications in total synthesis are discussed.
Date Issued
2018-10-01
Date Acceptance
2018-07-19
Citation
SYNTHESIS, 2018, 50 (20), pp.4008-4018
ISSN
0039-7881
Publisher
Thieme Publishing
Start Page
4008
End Page
4018
Journal / Book Title
SYNTHESIS
Volume
50
Issue
20
Copyright Statement
© 2018 Georg Thieme Verlag Stuttgart.
Subjects
Science & Technology
Physical Sciences
Chemistry, Organic
Chemistry
ortho-quinone methide
ortho-quinone methide imine
total synthesis
review
INTRAMOLECULAR 4+2 CYCLOADDITION
ENANTIOSELECTIVE TOTAL-SYNTHESIS
OXONIUM-PRINS CYCLIZATION
BRONSTED ACID CATALYSIS
AZA-ORTHO-XYLYLENES
BIOMIMETIC SYNTHESIS
ORGANIC-SYNTHESIS
BETA-DICARBONYLS
FORMAL SYNTHESIS
RING-SYSTEM
Publication Status
Published
Date Publish Online
2018-08-14