Siloxane-based linkers in the construction of hydrogen bonded assemblies and porous 3D MOFs
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Author(s)
Type
Journal Article
Abstract
A siloxane-based hexacarboxylic acid (L1-H6) has been prepared and applied in MOF construction. L1-H6 itself crystallizes as an unusual interpenetrated 3D hydrogen-bonded framework. Reaction of L1-H6 with Zn(II) gave IMP-18 – a 3D MOF incorporating Si–O–Si functionality. Cleavage of L1-H6 gives a silanol-based triacid which is shown to give a coordination polymer (IMP-19) with Zn(II).
Date Issued
2017-11-06
Date Acceptance
2017-09-22
Citation
Chemical Communications, 2017, 53, pp.12524-12527
ISSN
1359-7345
Publisher
Royal Society of Chemistry
Start Page
12524
End Page
12527
Journal / Book Title
Chemical Communications
Volume
53
Copyright Statement
This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
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Subjects
03 Chemical Sciences
Organic Chemistry
Publication Status
Published