Research Update: Relativistic origin of slow electron-hole recombination in hybrid halide perovskite solar cells
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Author(s)
Azarhoosh, P
McKechnie, S
Frost, JM
Walsh, A
Van Schilfgaarde, M
Type
Journal Article
Abstract
The hybrid perovskite CH3NH3PbI3 (MAPI) exhibits long minority-carrier lifetimes and diffusion lengths. We show that slow recombination originates from a spin-split indirect-gap. Large internal electric fields act on spin-orbit-coupled band extrema, shifting band-edges to inequivalent wavevectors, making the fundamental gap indirect. From a description of photoluminescence within the quasiparticle self-consistent GW approximation for MAPI, CdTe, and GaAs, we predict carrier lifetime as a function of light intensity and temperature. At operating conditions we find radiative recombination in MAPI is reduced by a factor of more than 350 compared to direct gap behavior. The indirect gap is retained with dynamic disorder.
Date Issued
2016-07-21
Date Acceptance
2016-06-14
Citation
APL Materials, 2016, 4 (9)
ISSN
2166-532X
Publisher
AIP Publishing
Journal / Book Title
APL Materials
Volume
4
Issue
9
Copyright Statement
© 2016 Author(s). All article content, except where otherwise noted, is licensed under a Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
License URL
Publication Status
Published
Article Number
091501