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  5. Measurement of physicochemical properties and CO2, N2, Ar, O2, and H2O unary adsorption isotherms of Purolite A110 and Lewatit VP OC 1065 for application in direct air capture
 
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Measurement of physicochemical properties and CO2, N2, Ar, O2, and H2O unary adsorption isotherms of Purolite A110 and Lewatit VP OC 1065 for application in direct air capture
File(s)
low-et-al-2023-measurement-of-physicochemical-properties-and-co2-n2-ar-o2-and-h2o-unary-adsorption-isotherms-of.pdf (4.6 MB)
Published version
Author(s)
Low, May-Yin Ashlyn
Danaci, David
Azzan, Hassan
Woodward, Robert T
Petit, Camille
Type
Journal Article
Abstract
Direct air capture (DAC) using solid adsorbents has gained significant attention as a carbon dioxide removal (CDR) technology to help limit global temperature rise to below 2 °C. One large area of focus is the development of new adsorbent materials for DAC. However, the necessary data needed to employ these materials in process models for adsorbent screening are rarely available. Here, we showcase Purolite A110, a commercially available amine-functionalized polymeric resin, as a new candidate adsorbent for DAC and compare its properties to a current benchmark, Lewatit VP OC 1065. For both materials, we report their chemical features and composition, skeletal, particle, and bed density, total pore volume, particle porosity, BET area, thermal stability, and specific heat capacity. We determine their equilibrium sorption properties by measuring the volumetric CO2 isotherms at 288, 298, 308, 333, 343, 353, and 393 K, N2 and H2O isotherms at 288, 298, and 308 K, and Ar and O2 isotherms at 298 K. For CO2, N2, and H2O, we also present the corresponding isotherm model fitting parameters and heats of adsorption. These data can help facilitate process modeling and optimization studies to properly assess these adsorbents at scale.
Date Issued
2023-12-14
Date Acceptance
2023-09-18
Citation
Journal of Chemical and Engineering Data, 2023, 68 (12), pp.3499-3511
URI
http://hdl.handle.net/10044/1/108709
URL
https://pubs.acs.org/doi/10.1021/acs.jced.3c00401
DOI
https://www.dx.doi.org/10.1021/acs.jced.3c00401
ISSN
0021-9568
Publisher
American Chemical Society
Start Page
3499
End Page
3511
Journal / Book Title
Journal of Chemical and Engineering Data
Volume
68
Issue
12
Copyright Statement
Copyright © 2023 The Authors. Published by American Chemical Society. This publication is licensed under
CC-BY 4.0.
License URL
https://creativecommons.org/licenses/by/4.0/
Identifier
https://www.ncbi.nlm.nih.gov/pubmed/38115913
Publication Status
Published
Coverage Spatial
United States
Date Publish Online
2023-10-11
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