Filling transitions in acute and open wedges.
File(s)PhysRevE.91.052401.pdf (1.13 MB)
Published version
Author(s)
Malijevský, A
Parry, AO
Type
Journal Article
Abstract
We present numerical studies of first-order and continuous filling transitions in wedges of arbitrary opening angle ψ, using a microscopic fundamental measure density functional model with short-ranged fluid-fluid forces and long-ranged wall-fluid forces. In this system the wetting transition characteristic of the planar wall-fluid interface is always first order regardless of the strength of the wall-fluid potential ɛ(w). In the wedge geometry, however, the order of the filling transition depends not only on ɛ(w) but also on the opening angle ψ. In particular we show that even if the wetting transition is strongly first order the filling transition is continuous for sufficient acute wedges. We show further that the change in the order of the transition occurs via a tricritical point as opposed to a critical end point. These results extend previous effective Hamiltonian predictions which were limited only to shallow wedges.
Date Issued
2015-05-11
Date Acceptance
2015-02-26
Citation
Physical Review E, 2015, 91 (5), pp.052401-1-052401-8
ISSN
2470-0045
Publisher
American Physical Society
Start Page
052401-1
End Page
052401-8
Journal / Book Title
Physical Review E
Volume
91
Issue
5
Copyright Statement
©2015 American Physical Society
Sponsor
Engineering & Physical Science Research Council (EPSRC)
Engineering & Physical Science Research Council (EPSRC)
Grant Number
EP/I019111/1
EP/J009636/1
Subjects
Science & Technology
Physical Sciences
Physics, Fluids & Plasmas
Physics, Mathematical
Physics
PHASE-EQUILIBRIA
NARROW PORES
FLUIDS
CAPILLARY
BEHAVIOR
Fluids & Plasmas
01 Mathematical Sciences
02 Physical Sciences
09 Engineering
Publication Status
Published