Negative area compressibility in silver(i) tricyanomethanide

File(s)

c3cc47032f.pdf (1.27 MB)

Published version

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Author(s)

Hodgson, Sarah A

Adamson, Jasper

Hunt, Sarah J

Cliffe, Matthew J

Cairns, Andrew B

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Type

Journal Article

Abstract

The molecular framework Ag(tcm) (tcm− = tricyanomethanide) expands continuously in two orthogonal directions under hydrostatic compression. The first of its kind, this negative area compressibility behaviour arises from the flattening of honeycomb-like layers during rapid pressure-driven collapse of the interlayer separation.

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Date Issued

2014-05-25

Date Acceptance

2013-12-09

Citation

Chemical Communications, 2014, 50 (40), pp.5264-5266

URI

http://hdl.handle.net/10044/1/109764

URL

https://pubs.rsc.org/en/content/articlelanding/2014/cc/c3cc47032f

DOI

https://www.dx.doi.org/10.1039/c3cc47032f

ISSN

1359-7345

Publisher

Royal Society of Chemistry

Start Page

5264

End Page

5266

Journal / Book Title

Chemical Communications

Volume

50

Issue

40

Copyright Statement

This journal is © The Royal Society of Chemistry 2014. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.

License URL

https://creativecommons.org/licenses/by/3.0/

Identifier

https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000828703900001&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=a2bf6146997ec60c407a63945d4e92bb

Subjects

ANISOTROPIC THERMAL-EXPANSION

Chemistry

Chemistry, Multidisciplinary

LINEAR COMPRESSIBILITY

Physical Sciences

Science & Technology

Publication Status

Published

Date Publish Online

2013-12-09