Modelling optimum thickness and architecture for lithium-ion battery cathodes
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Published version
Author(s)
Imediegwu, Chikwesiri
Shaffer, Milo SP
Ryan, Mary P
Panesar, Ajit
Type
Journal Article
Abstract
Commercial lithium-ion battery (LIB) electrodes traditionally comprise a homogeneous layer of stochastically mixed constituent materials. However, a significant barrier to cell performance is attributed to the architecture of the electrode; the trade-off between useful capacity and rate capability limits the cell performance during fast charging or discharging. This study develops a continuum model to emulate the behaviour of these electrodes. It presents optimal electrode thickness and active material (AM) volume fraction values that maximise cell performance for slurry-cast electrodes. Finally, the study demonstrates that by patterning the electrode architecture, volumetric energy density can be significantly improved, subject to manufacturing constraints, and provides quantitative design guidelines for future study.
Date Issued
2024-09-15
Date Acceptance
2024-06-28
Citation
Journal of Power Sources, 2024, 614
ISSN
0378-7753
Publisher
Elsevier BV
Journal / Book Title
Journal of Power Sources
Volume
614
Copyright Statement
© 2024 The Author(s). Published by Elsevier B.V. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).
License URL
Identifier
http://dx.doi.org/10.1016/j.jpowsour.2024.235005
Publication Status
Published
Article Number
235005
Date Publish Online
2024-07-17