Tunable phase gratings by wrinkling of plasma-oxidized PDMS: gradient skins and multiaxial patterns
File(s)Tan Tunable Diffraction PDMS 7 Sep 2021.pdf (1.78 MB)
Accepted version
Author(s)
Tan, Annabelle
Pellegrino, Luca
Cabral, Joao T
Type
Journal Article
Abstract
Wrinkling instabilities in polymeric bilayers have been exploited as optical phase gratings with tunable performance. Here, we report strain modulated 1D and 2D phase gratings fabricated by the ubiquitous process of plasma-oxidation of polydimethylsiloxane (PDMS). While surface oxidation provides a remarkably facile glassy skin formation approach, minimizing delamination and debonding, it inherently results in a gradient conversion profile emanating from the top film interface. We examine and quantitatively model the consequences of this gradient layer on the optical properties of the resulting strain-tunable phase gratings. Diffraction efficiencies up to 48% are demonstrated. We then develop and validate a surface reconstruction methodology based on the diffraction pattern of our sinusoidal gratings and our model, which we extend to the high deformation regimes and to 2D gratings, obtained by superposition of two wrinkling generations, where both amplitudes and wavelengths can be independently tuned. Overall, this approach provides a rapid, robust and predictive framework for the design and fabrication of tunable, single, and multiaxial surface gratings.
Date Issued
2021-09-15
Date Acceptance
2021-09-01
Citation
ACS Applied Polymer Materials, 2021, 3 (10), pp.5162-5170
ISSN
2637-6105
Publisher
American Chemical Society
Start Page
5162
End Page
5170
Journal / Book Title
ACS Applied Polymer Materials
Volume
3
Issue
10
Copyright Statement
Copyright © 2021 American Chemical Society
Identifier
http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000707982700040&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=1ba7043ffcc86c417c072aa74d649202
Subjects
Science & Technology
Technology
Physical Sciences
Materials Science, Multidisciplinary
Polymer Science
Materials Science
PDMS
wrinkling plasma oxidation
phase grating diffraction
optics
THIN-FILMS
ORDERED STRUCTURES
SURFACE
POLYDIMETHYLSILOXANE
OXIDATION
COMPLEX
Publication Status
Published