Efficient multicomponent active template synthesis of catenanes
File(s)
Author(s)
Lewis, James EM
Modicom, Florian
Goldup, Stephen M
Type
Journal Article
Abstract
We describe a simple and high yielding active template synthesis of [2]catenanes. In addition to mechanical bond formation using a single premacrocycle bearing an azide and alkyne moiety, our method is also suitable for the co-macrocyclization of readily available bis-alkyne and bis-azide comonomers and even short alkyne/azide components which oligomerize prior to mechanical bond formation.
Date Issued
2018-04-11
Date Acceptance
2018-03-18
Citation
Journal of the American Chemical Society, 2018, 140 (14), pp.4787-4791
ISSN
1520-5126
Publisher
American Chemical Society
Start Page
4787
End Page
4791
Journal / Book Title
Journal of the American Chemical Society
Volume
140
Issue
14
Copyright Statement
© 2018 American Chemical Society. This is an open access article published under a Creative Commons Attribution (CC-BY - https://creativecommons.org/licenses/by/4.0/) License, which permits unrestricted use, distribution and reproduction in any medium, provided the author and source are cited.
Identifier
http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000430155800009&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=1ba7043ffcc86c417c072aa74d649202
Subjects
Science & Technology
Physical Sciences
Chemistry, Multidisciplinary
Chemistry
MECHANICALLY INTERLOCKED MOLECULES
MACHINES NOBEL LECTURE
EMERGING APPLICATIONS
INFORMATION RATCHET
DIRECTED SYNTHESIS
ANION RECOGNITION
PEPTIDE-SYNTHESIS
EXCELLENT YIELD
ROTAXANES
MACROCYCLES
Publication Status
Published
Date Publish Online
2018-03-20