Formation of magnetic minerals in hydrocarbon-generation conditions
File(s)Abubakar_Formation_of_magnetic.pdf (2.84 MB)
Published version
Author(s)
Type
Journal Article
Abstract
In this paper, we report the pyrolysis and formation of magnetic minerals in three source rock samples from the Wessex Basin in Dorset, southern England. The experimental conditions in the laboratory recreated the catagenesis environment of oil source rocks. Magnetic analysis of both the heated and the unheated samples at room temperature and at very low temperatures (5 K), coupled with transmission electron-microscopy imaging and X-ray analysis, revealed the formation of nanometre-sized (<10 nm), magnetic particles that varied across the rock samples analysed, but more importantly across the pyrolysis temperature range. Magnetic measurements demonstrated the formation of these magnetic minerals peaked at 250 °C for all rock samples and then decreased at 300 °C before rising again at 320 °C. The newly formed magnetic minerals are suggested to be primarily pyrrhotite, though magnetite and greigite are also thought to be present. The sizes of the magnetic minerals formed suggest a propensity to migrate together with oil potentially explaining the magnetic anomalies observed above and within oil fields.
Date Issued
2015-10-09
Date Acceptance
2015-10-02
Citation
Marine and Petroleum Geology, 2015
ISSN
1873-4073
Publisher
Elsevier
Start Page
509
End Page
519
Journal / Book Title
Marine and Petroleum Geology
Volume
68
Issue
Part A
Copyright Statement
© 2015 The Authors. Published by Elsevier B.V. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).
License URL
Identifier
http://www.sciencedirect.com/science/article/pii/S0264817215301045
Publication Status
Published
Coverage Spatial
Cambridge