Deformation behaviour of TiN and Ti–Al–N coatings at 295 to 573 K
File(s)1-s2.0-S0040609019303827-main.pdf (1.3 MB)
Published version
Author(s)
Type
Journal Article
Abstract
Temperature-dependent nanoindentation testing was employed to investigate the deformation behaviour of magnetron sputtered (100) TiN and Ti1-xAlxN (x = 0.34, 0.52, 0.62) coatings in the temperature range from 295 to 573 K. The maximum temperature is sufficiently below the deposition temperature of 773 K to guarantee for stable microstructure and stress state during testing. The TiN coating displayed the same hardness as bulk single crystal (SC) TiNbulk. The addition of aluminium to TiN (to form single-phase face centred cubic structured Ti1-xAlxN coatings) increased the room temperature hardness due to increased bond strength, lattice strain and higher activation energy for the dislocation slip. For coatings with a low aluminium content, Ti0.66Al0.34N, the decrease in hardness with temperature was similar to the TiN coating and SC-TiNbulk. In contrast, the hardness of coatings with moderate, Ti0.48Al0.52N, and high, Ti0.38Al0.62N, aluminium contents varied little up to 573 K. Thus, the Ti1-xAlxN matrix is mechanically more stable at elevated temperatures than its TiN relative, by providing a lower decrease in lattice resistance to the dislocation flow with increasing temperature. The findings suggest that the addition of Al to TiN (to form Ti1-xAlxN solid solutions) not only improves the hardness but also leads to stable hardness with temperature, and emphasizes the importance of bonding states and chemical fluctuations, next to structure and morphology of the coatings that develop with changing the chemistry.
Date Issued
2019-10-31
Date Acceptance
2019-06-09
Citation
Thin Solid Films, 2019, 688
ISSN
0040-6090
Publisher
Elsevier
Journal / Book Title
Thin Solid Films
Volume
688
Copyright Statement
© 2019 The Authors. Published by Elsevier B.V. This is an open access article under the CC BY-NC-ND license
(http://creativecommons.org/licenses/BY-NC-ND/4.0/).
(http://creativecommons.org/licenses/BY-NC-ND/4.0/).
Sponsor
Seco Tools AB
Grant Number
TC / Andreas Larsson
Subjects
Science & Technology
Technology
Physical Sciences
Materials Science, Multidisciplinary
Materials Science, Coatings & Films
Physics, Applied
Physics, Condensed Matter
Materials Science
Physics
Titanium aluminium nitride
Strength
Peierls barrier
Lattice resistance
Temperature-dependent hardness
TRANSMISSION ELECTRON-MICROSCOPY
MECHANICAL-PROPERTIES
THERMAL-STABILITY
MICROSTRUCTURAL EVOLUTION
SPINODAL DECOMPOSITION
PHASE-TRANSITIONS
DEFECT STRUCTURE
HARD COATINGS
PERFORMANCE
TI1-XALXN
02 Physical Sciences
09 Engineering
10 Technology
Applied Physics
Publication Status
Published
Article Number
ARTN 137363
Date Publish Online
2019-06-10