The importance of accurate determination of optical constants for the design of nanometallic light-trapping structures
File(s)Manuscript_review.pdf (816.82 KB)
Accepted version
Author(s)
Pearce, Phoebe
Mellor, Alexander
Ekins-Daukes, Nicholas
Type
Journal Article
Abstract
The optical constants of many metals commonly used in solar cells, e.g. as contacts, rear side planar reflectors, or more complex nanopatterned light-trapping structures, can vary depending on deposition method, thickness and other factors, and as such are not documented consistently in the literature. In the case of nanometallic light-trapping structures specifically designed to improve absorption in a solar cell, the choice of optical constants used in simulations significantly affects the predicted enhancement, as well as the structure's optimal dimensions. The trade-off between coupling into guided modes in the photovoltaic material and the number of photons absorbed parasitically in the metal leads to small differences in the optical constants giving significantly different results for the quantum efficiency and photogenerated current. This work documents several optical constant sources for silver, aluminium, gold and titanium, and the effect this has on plasmon quality factors. The effect of choosing different optical constant sources on modelling outcomes is quantified by considering the optimization of a test structure comprising a grid of metal nanodisks on the front surface of a thinned-down GaAs cell. Finally, we define a new spectrally-integrated figure of merit for comparing the expected performance of metals in light-trapping structures based on their optical constants, which we name the spectral absorption enhancement factor (SAEF).
Date Issued
2019-03-01
Date Acceptance
2018-11-06
Citation
Solar Energy Materials and Solar Cells, 2019, 191, pp.133-140
ISSN
0927-0248
Publisher
Elsevier
Start Page
133
End Page
140
Journal / Book Title
Solar Energy Materials and Solar Cells
Volume
191
Copyright Statement
© 2019 Elsevier Ltd. All rights reserved. This manuscript is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International Licence http://creativecommons.org/licenses/by-nc-nd/4.0/
Identifier
http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000456640000018&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=1ba7043ffcc86c417c072aa74d649202
Subjects
Science & Technology
Technology
Physical Sciences
Energy & Fuels
Materials Science, Multidisciplinary
Physics, Applied
Materials Science
Physics
Light-trapping
RCWA
Ultra-thin solar cells
Metallic gratings
Surface plasnions
SOLAR-CELLS
PLASMONICS
SCATTERING
FILMS
Publication Status
Published
Date Publish Online
2018-11-20