An insight on the effect of azobenzene functionalities studied in UiO-66 framework for low energy CO2 capture and CO2/N2 membrane separation
File(s)
Published version
Author(s)
Prasetya, Nicholaus
Ladewig, Bradley P
Type
Journal Article
Abstract
In this paper, a simple approach to study the fundamental aspect of light-responsive metal organic framework (MOF) in UiO-66 topology through mixed-ligand approach is reported. Apart from change in the structural property, the loading of azobenzene linker inside the framework also affects the CO2 light-responsive property and CO2/N2 selectivity which could help to design the future low-energy CO2 adsorbent. Further study to incorporate the MOFs into mixed matrix membranes using PIM-1 as the polymer matrix also indicates the benefits of having higher azobenzene loading in the MOF to enhance the CO2/N2 separation performance since it can improve the separation performance that could not be obtained in non-functionalized fillers.
Date Issued
2019-05-22
Date Acceptance
2019-05-21
Citation
Journal of Materials Chemistry A, 2019, 7 (25), pp.15164-15172
ISSN
2050-7496
Publisher
Royal Society of Chemistry
Start Page
15164
End Page
15172
Journal / Book Title
Journal of Materials Chemistry A
Volume
7
Issue
25
Copyright Statement
© The authors. This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence (https://creativecommons.org/licenses/by-nc/3.0/). Material from this article can be used in other publications provided that the correct acknowledgement is given with the reproduced material and it is not used for commercial purposes.
Identifier
https://pubs.rsc.org/en/content/articlelanding/2019/TA/C9TA02096A#!divAbstract
Subjects
Science & Technology
Physical Sciences
Technology
Chemistry, Physical
Energy & Fuels
Materials Science, Multidisciplinary
Chemistry
Materials Science
MIXED-MATRIX MEMBRANES
METAL-ORGANIC FRAMEWORKS
INTRINSIC MICROPOROSITY
GAS SEPARATION
ADSORPTION
POLYMER
ROUTE
PIM-1
SELECTIVITY
PERMEATION
0303 Macromolecular and Materials Chemistry
Publication Status
Published
Date Publish Online
2019-05-22