A comparative study of transient flow rate steps and ramps for the efficient collection of kinetic data
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Author(s)
Type
Journal Article
Abstract
Transient cumulative flow rate varying methods have proven very effective for the collection of residence time series data for reactions in continuous flow. In this study, comparisons will be made between data collected from step changes and linear flow rate ramps, to inform method choice and minimise the complexity of automation and control needed to implement these methods, without compromising the quality of the data. Using two different analytical tools (in-line FTIR and on-line HPLC), the methods were compared in two different flow system configurations, and across three chemical reactions of increasing complexity. This work finds that the quality of the data collected using simpler step changes are comparable to that collected using more complex ramping methods, when performed in a reverse push-out (high to low flow rate) manner.
Date Issued
2024-05-01
Date Acceptance
2024-02-08
Citation
Reaction Chemistry and Engineering, 2024, 9 (5), pp.1077-1086
ISSN
2058-9883
Publisher
Royal Society of Chemistry
Start Page
1077
End Page
1086
Journal / Book Title
Reaction Chemistry and Engineering
Volume
9
Issue
5
Copyright Statement
This journal is © The Royal Society of Chemistry 2024. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
License URL
Identifier
http://dx.doi.org/10.1039/d3re00696d
Publication Status
Published
Date Publish Online
2024-02-08