Crystal structure of trans-1,4-bis-[(trimethylsilyl)oxy]cyclohexa-2,5-diene-1,4-dicarbonitrile
Author(s)
Glöcklhofer, Florian
Fröhlich, Johannes
Stöger, Berthold
Weil, Matthias
Type
Journal Article
Abstract
The asymmetric unit of the title compound, C14H22N2O2Si2, contains one half of the mol-ecule, which is completed by inversion symmetry. The cyclo-hexa-2,5-diene ring is exactly planar and reflects the bond-length distribution of a pair of located double bonds [1.3224 (14) Å] and two pairs of single bonds [1.5121 (13) and 1.5073 (14) Å]. The tetra-hedral angle between the sp (3)-C atom and the two neighbouring sp (2)-C atoms in the cyclo-hexa-2,5-diene ring is enlarged by about 3°.
Date Issued
2014-08-01
Date Acceptance
2014-06-17
Citation
Acta Crystallogr Sect E Struct Rep Online, 2014, 70 (Pt 8), pp.77-79
ISSN
1600-5368
Start Page
77
End Page
79
Journal / Book Title
Acta Crystallogr Sect E Struct Rep Online
Volume
70
Issue
Pt 8
Copyright Statement
© 2014 International Union of Crystallography. This licence is a Creative Commons Attribution (CC-BY) Licence, which provides for the re-use of the article in whole or part provided there is attribution for the article. (https://creativecommons.org/licenses/by/4.0/legalcode)
Identifier
https://www.ncbi.nlm.nih.gov/pubmed/25249859
PII: su0009
Subjects
crystal structure
Cyanohydrin
cyclohexa-2,5-diene
Publication Status
Published online
Coverage Spatial
United States
Date Publish Online
2014-08-01