Dynamic fracture resistance under plane strain conditions of high-density polyethylene nanoclay composites
Author(s)
López-Cabrera, HR
Figueroa-López, U
Taylor, AC
Guevara-Morales, A
Type
Journal Article
Abstract
Polymer nanoclay composites have received significant attention due to their substantially enhanced mechanical, thermal and barrier properties. However, the effect of these nanoclays on the dynamic fracture resistance of a polymer matrix during fast fracture events has not been documented. In this study, the effect of nanoclay addition on the rapid crack propagation (RCP) resistance of high-density polyethylene (HDPE) was investigated through the high-speed double torsion test. Results showed that the addition of 1, 3, and 5% of nanoclays improved the dynamic fracture resistance under the plane strain conditions (Gd1) of HDPE up to 65%. An increase in the storage and loss modulus, and a decrease in crystallinity and melt flow index with nanoclay content was also found. Although the presence of agglomerates can hinder the enhancement of Gd1 as it promotes agglomerate fracture and debonding, the increase in energy consumption through fibrillation and crazing promoted by the nanoclay prevails, suggesting that the nanoclay's toughening effect that has been extensively reported under quasi-static and impact tests, is also present under RCP conditions, and that the HDPE nanocomposites could be used in applications in which RCP must be prevented.
Date Issued
2023-02-06
Date Acceptance
2023-01-27
Citation
Polymers, 2023, 15 (4), pp.1-15
ISSN
2073-4360
Publisher
MDPI AG
Start Page
1
End Page
15
Journal / Book Title
Polymers
Volume
15
Issue
4
Copyright Statement
© 2023 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
License URL
Identifier
https://www.ncbi.nlm.nih.gov/pubmed/36850096
PII: polym15040813
Subjects
crazing
dynamic fracture resistance
high-speed double torsion test
montmorillonite nanoclays
polymer nanocomposites
rapid crack propagation
Publication Status
Published
Coverage Spatial
Switzerland
Article Number
813
Date Publish Online
2023-02-06