Jet aircraft lubrication oil droplets as contrail ice-forming particles
File(s)acp-24-2045-2024.pdf (2.57 MB)
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Author(s)
Ponsonby, Joel
King, Leon
Murray, Benjamin J
Stettler, Marc EJ
Type
Journal Article
Abstract
The radiative characteristics and lifetimes of contrails are dependent on the number concentration of ice-forming particles in the engine exhaust plume. Aircraft gas turbine engines produce a variety of particles, yet it is understood that non-volatile black carbon aggregates are the dominant source of ice-forming particles with typical, fossil-derived jet fuel. However, with cleaner combustion technologies and the adoption of alternative fuels (e.g. hydrogen or synthetic aviation fuel), non-volatile black carbon particle emissions are expected to decrease or even be eliminated. Under these conditions, contrail properties will depend upon the concentration and characteristics of particles other than black carbon. Ultrafine (< 100 nm) jet lubrication oil droplets constitute a significant fraction of the total organic particulate matter released by aircraft; however, their ability to form contrail ice crystals has hitherto been unexplored. In this work, we experimentally investigate the activation and freezing behaviour of lubrication oil droplets using an expansion chamber, assessing their potential as ice-forming particles. We generate lubrication oil droplets with a geometric mean mobility diameter of (100.9 ± 0.6) nm and show that these activate to form water droplets, which subsequently freeze when the temperature is below ∼ 235 K. We find that nucleation on lubrication oil droplets should be considered in future computational studies – particularly under soot-poor conditions – and that these studies would benefit from particle size distribution measurements at cruise altitude. Overall, taking steps to reduce lubrication oil number emissions would help reduce the climate impact of contrail cirrus.
Date Issued
2024-02-16
Date Acceptance
2023-11-03
Citation
Atmospheric Chemistry and Physics, 2024, 24 (3), pp.2045-2058
ISSN
1680-7316
Publisher
Copernicus Publications
Start Page
2045
End Page
2058
Journal / Book Title
Atmospheric Chemistry and Physics
Volume
24
Issue
3
Copyright Statement
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License (https://creativecommons.org/licenses/by/4.0/)
the Creative Commons Attribution 4.0 License (https://creativecommons.org/licenses/by/4.0/)
License URL
Identifier
http://dx.doi.org/10.5194/acp-24-2045-2024
Publication Status
Published
Date Publish Online
2024-02-16