Low-temperature specific heat in hydrogenated and Mn-doped La(Fe, Si)(13)
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Accepted version
Author(s)
Type
Journal Article
Abstract
It is now well established that the paramagnetic-to-ferromagnetic transition in the magnetocaloric La(FeSi)13 is a cooperative effect involving spin, charge, and lattice degrees of freedom. However, the influence of this correlated behavior on the ferromagnetic state is as yet little studied. Here we measure the specific heat at low temperatures in a systematic set of LaFexMnySiz samples, with and without hydrogen, to extract the Sommerfeld coefficient, the Debye temperature, and the spin-wave stiffness. Substantial and systematic changes in magnitude of the Sommerfeld coefficient are observed with Mn substitution and introduction of hydrogen, showing that over and above the changes to the density of states at the Fermi energy there are significant enhanced d-band electronic interactions at play. The Sommerfeld coefficient is found to be 90–210mJmol−1K−2, unusually high compared to that expected from band-structure calculations. The Debye temperature determined from the specific heat measurement is insensitive to Mn and Si doping but increases when hydrogen is introduced into the system. The Sommerfeld coefficient is reduced in magnetic field for all compositions that have a measurable spin-wave contribution. These results move our understanding of the cooperative effects forward in this important and interesting class of materials significantly and provide a basis for future theoretical development.
Date Issued
2016-10-05
Date Acceptance
2016-10-01
Citation
Physical Review B, 2016, 94
ISSN
2469-9950
Publisher
American Physical Society
Journal / Book Title
Physical Review B
Volume
94
Copyright Statement
©2016 American Physical Society
Sponsor
Engineering & Physical Science Research Council (EPSRC)
Engineering & Physical Science Research Council (EPSRC)
Commission of the European Communities
Identifier
http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000385239900001&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=1ba7043ffcc86c417c072aa74d649202
Grant Number
EP/E016243/1
EP/G060940/1
310748
Subjects
Science & Technology
Physical Sciences
Physics, Condensed Matter
Physics
ELECTRON METAMAGNETIC LA(FE0.88SI0.12)(13)H-Y
MAGNETIC ENTROPY CHANGES
MAGNETOCALORIC PROPERTIES
TRANSITION-METALS
ALLOYS
MAGNETOSTRICTION
STABILITY
COMPOUND
CAPACITY
CO
Publication Status
Published
Article Number
ARTN 134405