Influence of blend morphology and energetics on charge separation and recombination dynamics in organic solar cells incorporating a nonfullerene acceptor
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Accepted version
Supporting information
Author(s)
Type
Journal Article
Abstract
Nonfullerene acceptors (NFAs) in blends with highly crystalline donor polymers have been shown to yield particularly high device voltage outputs, but typically more modest quantum yields for photocurrent generation as well as often lower fill factors (FF). In this study, we employ transient optical and optoelectronic analysis to elucidate the factors determining device photocurrent and FF in blends of the highly crystalline donor polymer PffBT4T-2OD with the promising NFA FBR or the more widely studied fullerene acceptor PC71BM. Geminate recombination losses, as measured by ultrafast transient absorption spectroscopy, are observed to be significantly higher for PffBT4T-2OD:FBR blends. This is assigned to the smaller LUMO-LUMO offset of the PffBT4T-2OD:FBR blends relative to PffBT4T-2OD:PC71BM, resulting in the lower photocurrent generation efficiency obtained with FBR. Employing time delayed charge extraction measurements, these geminate recombination losses are observed to be field dependent, resulting in the lower FF observed with PffBT4T-2OD:FBR devices. These data therefore provide a detailed understanding of the impact of acceptor design, and particularly acceptor energetics, on organic solar cell performance. Our study concludes with a discussion of the implications of these results for the design of NFAs in organic solar cells.
Date Issued
2018-01-17
Date Acceptance
2017-09-28
Citation
Advanced Functional Materials, 2018, 28 (3)
ISSN
1616-301X
Publisher
Wiley
Journal / Book Title
Advanced Functional Materials
Volume
28
Issue
3
Copyright Statement
© 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. This is the pre-peer reviewed version of the article, which has been published in final form at https://dx.doi.org/10.1002/adfm.201704389
Sponsor
Engineering & Physical Science Research Council (EPSRC)
Engineering & Physical Science Research Council (E
Kaust
Engineering and Physical Sciences Research Council
Grant Number
EP/J021199/1
EP/M023532/1
CHEDG_P61719
EP/P032591/1
Subjects
Science & Technology
Physical Sciences
Technology
Chemistry, Multidisciplinary
Chemistry, Physical
Nanoscience & Nanotechnology
Materials Science, Multidisciplinary
Physics, Applied
Physics, Condensed Matter
Chemistry
Science & Technology - Other Topics
Materials Science
Physics
field-dependent generation
geminate recombination
nonfullerene acceptors
nongeminate recombination
organic solar cells
NON-FULLERENE
HIGH-EFFICIENCY
GEMINATE RECOMBINATION
ELECTRON-ACCEPTORS
POLYMER
PHOTOVOLTAICS
FILMS
DIFFUSION
MOBILITY
LOSSES
Publication Status
Published
Article Number
ARTN 1704389
Date Publish Online
2017-11-27