Stable bromoallene oxides
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Author(s)
Braddock, DC
Mahtey, A
Rzepa, HS
White, AJP
Type
Journal Article
Abstract
The first stable bromoallene oxides were obtained by the DMDO epoxidation of 1-bromo-1,3-di-tert-alkylallenes, producing the first crystalline allene oxide of any kind. The epoxidations are regioselective for the bromine-bearing Δ1,2 alkene, and also face selective producing single diastereomer E-olefin products.
Date Issued
2016-09-28
Date Acceptance
2016-08-22
Citation
Chemical Communications, 2016, 52 (75), pp.11219-11222
ISSN
1364-548X
Publisher
Royal Society of Chemistry
Start Page
11219
End Page
11222
Journal / Book Title
Chemical Communications
Volume
52
Issue
75
Copyright Statement
This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
License URL
Subjects
Organic Chemistry
Chemical Sciences
Publication Status
Published
Date Publish Online
2016-08-30